M5S7 – Calculating Kc and Kp

10

Calculating Kc & Kp

1 / 10

Consider the following equilibrium:

2SO2(g) + O2(g) <=>2SO3(g)

8.00 mol of SO2 was mixed with 5.00 mol of O2 and the mixture sealed in a heated vessel of volume of 1.00 dm3. The mixture was left until no further observable change in composition took place. At this point, 2.00 mol of O2 was present in the mixture and the pressure was recorded as 200 kPa.

Calculate the value Kc (in units: mol-1 dm3) under these conditions.

2 / 10

Consider the following equilibrium:

2SO2(g) + O2(g) <=>2SO3(g)

8.00 mol of SO2 was mixed with 5.00 mol of O2 and the mixture sealed in a heated vessel of volume of 1.00 dm3. The mixture was left until no further observable change in composition took place. The pressure was recorded as 200 kPa. At this point, 2.00 mol of O2 was present in the mixture.

Calculate the value of Kp (in units: kPa-1) under these conditions.

3 / 10

Consider the following equilibrium for the Haber-Bosch process:

3H2(g) + N2(g) <=>2NH3(g)

32.0 mol of H2 was combined with 12.0 mol of N2 and the mixture sealed and pressurised in a vessel of volume 2.00 dm3. The mixture was left until no further observable change in composition took place. At this point, 4.00 mol of NH3 was found to be present in the mixture. The pressure was recorded as 200 000 kPa.

Calculate the value of Kc (in units: mol-2 dm6) under these conditions.

4 / 10

Consider the following equilibrium for the Haber-Bosch process:

3H2(g) + N2(g) <=>2NH3(g)

32.0 mol of H2 was combined with 12.0 mol of N2 and the mixture sealed and pressurised in a vessel of volume 2.00 dm3. The mixture was left until no further observable change in composition took place. At this point, 4.00 mol of NH3 was found to be present in the mixture The pressure was recorded as 200 000 kPa.

Calculate the value of Kp (in units: kPa-2) under these conditions.

5 / 10

Consider the following equilibrium:

N2(g) + O2(g) <=>2NO(g)

5.00 x 10-3 mol of N2 was mixed with 4.00 x 10-3 mol of O2 and 11.0 x 10-3 mol of NO and the mixture sealed in a container. The volume of the container was 0.500 dm3. The mixture was left to form a stable equilibrium. At this point, 9.00 x 10-3 mol of NO was present in the mixture. The pressure was recorded as 45000 kpa

Calculate the value of Kc (no units) under these conditions.

6 / 10

Consider the following equilibrium:

N2(g) + O2(g) <=>2NO(g)

5.00 x 10-3 mol of N2 was mixed with 4.00 x 10-3 mol of O2 and 11.0 x 10-3 mol of NO and the mixture sealed in a container. The volume of the container was 0.500 dm3. The mixture was left to form a stable equilibrium. At this point, 9.00 x 10-3 mol of NO was present in the mixture. The pressure was recorded as 45000 kpa

Calculate the value of Kp (no units) under these conditions.

7 / 10

Consider the following equilibrium:

3Fe(s) + 4H2O(g) <=>Fe3O4(s)+ 4H2(g)

40.0 g of iron wool was placed in a vessel of volume 2.00 dm3. The iron was exposed to 20.0 mol of high pressure steam and the system allowed to settle to equilibrium. At equilibrium, 0.250 mol of hydrogen was found in the vessel. The gauge on the pressure vessel read 1 000 kPa. The volume of iron wool was insignificant.

Calculate the value of Kc (no units) under these conditions.

8 / 10

Consider the following equilibrium:

3Fe(s) + 4H2O(g) Fe3O4(s)+ 4H2(g)

40.0 g of iron wool was placed in a vessel of volume 2.00 dm3. The iron was exposed to 20.0 mol of high pressure steam and the system allowed to settle to equilibrium. At equilibrium, 0.250 mol of hydrogen was found in the vessel. The gauge on the pressure vessel read 1 000 kPa. The volume of iron wool was insignificant.

Calculate the value of Kp (no units) under these conditions.

9 / 10

Consider the following equilibrium for the reaction that generates hydrogen for use in the Haber-Bosch Process:

CH4(g) + H2O(g) CO(g) + 3H2(g)

100 mol of CH4 was mixed with 100 mol of H2O and 200 mol of H2.The mixture was given time to reach equilibrium. At this point, 350 mol of H2 was present in the mixture. The pressure inside the 1.20 m3 vessel was measured as 400 kPa

Calculate the value of Kc (in units: mol2 dm-6) under these conditions.

10 / 10

Consider the following equilibrium for the reaction that generates hydrogen for use in the Haber-Bosch Process:

CH4(g) + H2O(g) <=>CO(g) + 3H2(g)

100 mol of CH4 was mixed with 100 mol of H2O and 200 mol of H2.The mixture was given time to reach equilibrium. At this point, 350 mol of H2 was present in the mixture. The pressure inside the 1.20 m3 vessel was measured as 400 kPa

Calculate the value of Kp (in units: kPa2) under these conditions.

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