M5S11 – Entropy and Gibbs Energy

9

Entropy and Gibbs Energy

1 / 10

Look at the chemical equation below.

2NaHCO3(s)=> Na2CO3(s)+ H2O(g)+ CO2(g)

By selecting the appropriate data from the ‘Selection of Thermodynamic Data’ in TOOLS, calculate the entropy change, ΔSƟ for the process. Take care with states!

2 / 10

Look at the chemical equation below.

2NaHCO3(s)=> Na2CO3(s)+ H2O(g)+ CO2(g)

By selecting the appropriate data from the ‘Selection of Thermodynamic Data’ in TOOLS, calculate the enthalpy change ΔHƟ for the process. Take care with states!

3 / 10

Look at the chemical equation below.

2NaHCO3(s)=> Na2CO3(s)+ H2O(g)+ CO2(g)

Using your answers to Questions 1 and 2, calculate the Gibbs Energy change, ΔG, for the process if it is carried out in an oven at 100oC.

If this question is from a Random Retrieval, you can also carry out this calculation by first working out values for ΔSƟ and ΔHƟ by selecting the appropriate data from the ‘Selection of Thermodynamic Data’ in TOOLS.

4 / 10

From your calculation of ΔG in question 3, decide whether a solid dry sample of NaHCO3(s) will decompose or will be thermally stable in the oven at 100oC.

If this question is from a Random Retrieval, you can also carry out this calculation of Gibbs Energy change, ΔG, by first working out values for ΔSƟ and ΔHƟ by selecting the appropriate data from the ‘Selection of Thermodynamic Data’ in TOOLS.

5 / 10

Look at the chemical equation below.

2NaHCO3(s)=> Na2CO3(s)+ H2O(g)+ CO2(g)

Calculate the temperature at which this process becomes feasible.

If this question is from a Random Retrieval, you can also carry out this calculation by first working out values for ΔSƟ and ΔHƟ by selecting the appropriate data from the ‘Selection of Thermodynamic Data’ in TOOLS.

6 / 10

Look at the chemical equation below.

CH4(g) + H2O(g)=> CO(g)+ 3H2(g)

By selecting the appropriate data from the ‘Selection of Thermodynamic Data’ in TOOLS, calculate the entropy change, ΔSƟ for the process. Take care with states!

7 / 10

Look at the chemical equation below.

CH4(g) + H2O(g)=> CO(g)+ 3H2(g)

By selecting the appropriate data from the ‘Selection of Thermodynamic Data’ in TOOLS, calculate the enthalpy change ΔHƟ for the process. Take care with states!

8 / 10

Look at the chemical equation below.

CH4(g) + H2O(g)=> CO(g)+ 3H2(g)

Using your answers to Questions 6 and 7, calculate the Gibbs Energy change ΔG, for the process if it is carried out in a reactor vessel at 1500oC.

If this question is from a Random Retrieval, you can also carry out this calculation by first working out values for ΔSƟ and ΔHƟ by selecting the appropriate data from the ‘Selection of Thermodynamic Data’ in TOOLS.

9 / 10

From your calculation of ΔG in question 8, decide whether the reaction between high pressure steam and methane will be feasible at 1500oC.

If this question is from a Random Retrieval, you can also carry out this calculation of Gibbs Energy change, ΔG by first working out values for ΔSƟ and ΔHƟ by selecting the appropriate data from the ‘Selection of Thermodynamic Data’ in TOOLS.

10 / 10

Look at the chemical equation below.

CH4(g) + H2O(g)=> CO(g)+ 3H2(g)

Calculate the temperature at which this process just becomes feasible.

If this question is from a Random Retrieval, you can also carry out this calculation by first working out values for ΔSƟ and ΔHƟ by selecting the appropriate data from the ‘Selection of Thermodynamic Data’ in TOOLS.

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